As it is anti-inflammatory, it can help to soothe and calm the skin.
Vitamin E can also help the skin to repair and protect its barrier (the barrier protects the skin against bacteria, allergens and prevents trans-epidermal water loss) by hydrating the upper layer of skin, therefore improving water-binding capacity.
We can say Vitamin E is an all-rounder vitamin, as it can help with skin hydration, as well as helping to protect the skin against sun damage and free radicals.